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A high-rate and long-life organic–oxygen battery

A high-rate and long-life organic–oxygen battery



Alkali metal–oxygen batteries promise high gravimetric energy densities but suffer from low rate capability, poor cycle life and safety hazards associated with metal anodes.

Here we describe a safe, high-rate and long-life oxygen battery that exploits a potassium biphenyl complex anode and a dimethylsulfoxide-mediated potassium superoxide cathode.

The proposed potassium biphenyl complex–oxygen battery exhibits an unprecedented cycle life (3,000 cycles) with a superior average coulombic efficiency of more than 99.84% at a high current density of 4.0 mA cm−2. We further reduce the redox potential of biphenyl by adding the electron-donating methyl group to the benzene ring, which successfully achieved a redox potential of 0.14 V versus K/K+. This demonstrates the direction and opportunities to further improve the cell voltage and energy density of the alkali-metal organic–oxygen batteries.

Data availability

Data supporting the findings of this study are available from the corresponding author upon reasonable request.

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Source: nature
Anand Gupta Editor - EQ Int'l Media Network


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